Non-local polymerization driven diffusion based model: general dependence of the polymerization rate to the exposure intensity.

نویسندگان

  • C Neipp
  • A Beléndez
  • J Sheridan
  • J Kelly
  • F O'Neill
  • S Gallego
  • M Ortuño
  • I Pascual
چکیده

The nonlocal diffusion model proposed by Sheridan and coworkers has provided a useful interpretation of the nature of grating formation inside photopolymer materials. This model accounts for some important experimental facts, such as the cut-off of diffraction efficiency for high spatial frequencies. In this article we examine the predictions of the model in the case of a general dependence of the polymerisation rate with respect to the intensity pattern. The effects of this dependence on the different harmonic components of the polymerisation concentration will be investigated. The influence of the visibility on the different harmonic components will also be studied. These effects are compared to the effects of varying RD and sigmaD.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Modelling the catalyst fragmentation pattern in relation to molecular properties and particle overheating in olefin polymerization

A two-dimensional single particle finite element model was used to examine the effects of particle fragmental pattern on the average molecular weights, polymerization rate and particle overheating in heterogeneous Ziegler-Natta olefin polymerization. A two-site catalyst kinetic mechanism was employed together with a dynamic two-dimensional molecular species in diffusion-reaction equation. The i...

متن کامل

Kinetics of ethylene polymerization over titanium-magnesium catalysts: The reasons for the observed second order of polymerization rate with respect to ethylene

The data on the effect of ethylene concentration on polymerization rate for several modifications of modern highly active titanium–magnesium catalysts TiCl4/MgCl2 are presented. These catalysts differ in titanium content and conditions of support preparation, activities, and the shape of kinetic curves. It is found that the observed order of polymerization rate with respect to ethylene in the r...

متن کامل

Simulation of Styrene Polymerization in Arbitrary Cross-Sectional Duct Reactors by Boundary-Fitted Coordinate Transformation Method

The non-orthogonal boundary-fitted coordinate transformation method is applied to the solution of steady three-dimensional conservation equations of mass, momentum, energy and speciescontinuity to obtain the laminar velocity, temperature and concentration fields for simulation of polymerization of styrene in arbitrary cross-sectional duct reactors. Variable physical properties (except for speci...

متن کامل

Modeling and Simulation of Olefin Polymerization at Microstructure Level

A new model based on a combination of the polymeric multigrain and multilayer models has been developed to predict the polymerization rate, particle growth, morphology, effective parameters on broadening of the molecular weight distribution, number and weight average of the molecular weight, isotacticity index and bulk density of polymer. Mathematical correlations and the kinetics used in t...

متن کامل

Impact of inhibitor diffusion in holographic photopolymers

Holographic photopolymers develop permanent index change via the polymerization and subsequent diffusion of monomer. It is well-known that to achieve high-fidelity recording, the rate of polymerization must be small in comparison to the rate of diffusion, particularly for strong exposures that consume significant fractions of the available monomer. When this condition is violated, polymerizatio...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Optics express

دوره 11 16  شماره 

صفحات  -

تاریخ انتشار 2003